3-Ethynyl-[1,10]phenanthroline

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3-Ethynyl-2,2,5,5-tetra­methyl-1-oxyl-3-pyrroline

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The title compound, C(10)H(11)NTe, is the first organyl ethynyl telluride, R-Te-C C-H, to be structurally characterized. In the L-shaped mol-ecule, the aryl moiety, viz. Me(2)NC(6)H(4)Te, is almost perpendicular to the Te-C C-H fragment. The Te-Csp(2) bond [2.115 (3) Å] is significantly longer than the Te-Csp bond [2.041 (4) Å]. The Te-C C group is approximately linear [Te-C-C = 178.5 (4)° and ...

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The asymmetric unit of the title compound, C20H15N, comprises two crystallographically independent mol-ecules (A and B). In each mol-ecule, the N atom adopts an approximately trigonal planar geometry, lying 0.009 (1) or 0.003 (1) Å from the plane defined by the C atoms of the aromatic substituents to which it is attached. In the crystal, mol-ecules are linked via C-H⋯π inter-actions, forming a ...

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In the title compound, C(21)H(24)O(2), rings B, C and D adopt half-chair, distorted half-chair and envelope conformations, respectively. In the crystal structure, there is an inter-molecular O-H⋯O hydrogen bond. The mol-ecules are arranged in a head-to-tail fashion, with the meth-oxy and hydr-oxy groups forming a two-dimensional hydrogen-bond network.

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ژورنال

عنوان ژورنال: Molecules

سال: 2001

ISSN: 1420-3049

DOI: 10.3390/m225